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Study of Distinguishing Metallic and Ionic Lithium in a Lithium-Ion Battery by an In Situ Imaging Technique with Muonic X-rays

Not scheduled
20m
Poster Presentation Energy storage materials Poster Session 1

Speaker

Shunsuke Asari (Osaka University)

Description

Repeated recharging of lithium-ion batteries leads to the deposition of metallic lithium (m-Li) on the anode surface. Visualizing the spatial distribution of m-Li is challenging with existing techniques. Furthermore, lithium can also be deposited in the form of insoluble salts (s-Li) within the battery, making it essential f for visualization methods that distinguish between these two lithium forms. In our study, we aim to develop a novel elemental imaging method based on muonic X-ray analysis. As a fundamental investigation, we conducted measurements at PSI to compare the muonic X-ray intensities of m-Li and s-Li compounds such as $\mathrm{LiF}$ and $\mathrm{Li_2CO_3}$. Our results show that the muonic X-ray intensity of m-Li is approximately 10 times greater than that of s-Li.
Additionally, we identified that the muonic X-rays generated in the surrounding air constitute the primary background. Our newly designed experimental setup can effectively reduce this interference, significantly improving detection sensitivity.

Email asari@rirc.osaka-u.ac.jp
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Primary author

Shunsuke Asari (Osaka University)

Co-authors

Dr Akira Sato (Osaka University) Dr Alex Amato (PSI Center for Neutron and Muon Sciences CNM, Switzerland) Dr Arndt Remhof (Swiss Federal Laboratories for Materials Science and Technology) Mr Hikaru Sunagawa (KEK (High Energy Accelerator Research Organization)) Dr Issa Briki (Paul Scherrer Institute) Dr Izumi Umegaki (KEK (High Energy Accelerator Research Organization)) Dr Michael Heiss (Paul Scherrer Institute) Mr Takahiro Yuasa (KEK (High Energy Accelerator Research Organization)) Dr Thomas Prokscha (Paul Scherrer Institute) Dr Xiao Zhao (Paul Scherrer Institute)

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