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$\beta$-NMR Study of Rutile TiO$_2$ and MgF$_2$ Supplemented by DFT

Not scheduled
20m
Poster Presentation Chemistry Poster session 2

Speaker

Signy L. Spencer (UBC and SBQMI)

Description

The rutile crystal structure contains vacant channels along the tetragonal $c$-axis that provide both sites and a diffusion path for small interstitial impurities. Here, we present beta-detected nuclear magnetic resonance ($\beta$-NMR) measurements of the quadrupole splitting of implanted $^8$Li$^+$ in two isostructural rutile single crystals: TiO$_2$ and MgF$_2$. We compare our results with supercell density functional theory (DFT) calculations to establish the crystallographic site of the implanted ion.

Email siggins4@icloud.com
Supervisors Name W. Andrew MacFarlane
Supervisors Email wam@chem.ubc.ca
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Primary author

Signy L. Spencer (UBC and SBQMI)

Co-authors

Andrew MacFarlane (UBC Chemistry) Dr Aris Chatzichristos (SBQMI and Department of Physics & Astronomy, University of British Columbia) Dr C. D. Philip Levy (TRIUMF) Derek Fujimoto (TRIUMF) Edward Thoeng (TRIUMF) Dr Gerald Morris (TRIUMF) Iain McKenzie (TRIUMF) John O. Ticknor (Department of Chemistry, University of British Columbia) Martin Dehn (UBC/TRIUMF) Matthew Pearson (TRIUMF) Monika Stachura (TRIUMF) Rob Kiefl Kiefl (TRIUMF and UBC) Ruohong Li (TRIUMF) Dr Ryan McFadden (TRIUMF Inc.) Dr S. M. Koohpayeh (William H. Miller III Department of Physics and Astronomy, Johns Hopkins University,) Sarah Dunsiger (TRIUMF / Simon Fraser University) Victoria L. Karner (TRIUMF)

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